Orange By-products
 

Although juice is the main product of oranges, many commercial value by-products are obtained during its processing phases, such as essential oils, d'limonene, terpenes, aromatic liquids and citrus pulp pellets (CPP).

They have different applications in the domestic and international markets, and include the production of chemical products and solvents, flavors and fragrances, substances for the paint industry, cosmetics, and animal feed supplements.

For more information on orange by-products, and their export data, please refer to the links below:

 
  Essential Oils
D'limonene
Citrus Pulp Pellets (CPP)


  Essential Oils

Essential oils are volatile oils removed from citrus fruit peel.

During the juice extraction process, oil sacs break, releasing the product that is then removed with a spray of water. The product is recovered by centrifugation and then cooled.

These oils are used more frequently in the food and pharmaceutical industries. They provide flavor to drinks, ice creams and other foods, in addition to being used in preparing pharmaceuticals, toilet soaps, perfumes and other cosmetics, and home care products.

Furthermore, there are by-products of essential oils, obtained by removing the oxidative compounds (such as d'limonene) and through the concentration of its aromatic fraction (by vacuum distillation). Concentrated essential oils are also used in the food and pharmaceutical industries.
Brazilian exports of Essential Oils
Season Export volume
(in tons)
Season Export volume
(in tons)
1996/97 19,159 2002/03 25,899
1997/98 24,454 2003/04 19,700
1998/99 26,954 2004/05 32,714
1999/00 18,575 2005/06 29,083
2000/01 21,739 2006/07 31,111
2001/02 20,790 2007/08 29,199
Source: Secex
 
   


  D'limonene

D'limonene is a colorless liquid, with a slight citric odor, obtained during juice extraction from the concentration of the lime treated citrus peel liquor.

The oil in the liquor is removed during evaporation and condensed separately. D'limonene is an oily fraction and is considered one of the purest sources of monocyclic terpene.

There are several applications for this product, among which industrial solvents, flavor and aromatic component and as raw material for the synthesis of other chemical compounds.

Some uses include solvents for resins, ester gum, rubber, pine oil derivatives, and others. It is used also as dispersing agent for oils, pigments, paints, printing inks etc. As flavor and aromatic component, d'limonene is used by the food and pharmaceutical industries for the production of menthol and artificial spearmint flavor for preparing candy, sweets, chewing gum and so on.
Brazilian exports of D'limonene
Season Export volume
(in tons)
Season Export volume
(in tons)
1996/97 41,044 2002/03 40,864
1997/98 34,314 2003/04 34,445
1998/99 33,929 2004/05 42,936
1999/00 35,560 2005/06 34,562
2000/01 43,274 2006/07 38,529
2001/02 30,336 2007/08 36,051
Source: Secex
 
   


  Citrus Pulp Pellets (CPP)

Once the juice has been extracted from oranges, peels and rags is left behind. They are equivalent to approximately 50% of the processed fruit's weight and will be converted into citrus pulp pellets to be used in cattle feed.

In the production process, calcium oxide is added to the peels and rags which are then crushed into small parts which range from 0,2 cm to 0,6 cm. These small parts go through a reactor for approximately 12 minutes where the mixing of the calcium oxide to the wet peel takes place generating the liberation of water. The wet peel enters the industrialization process at humidity of approximately 82% which is reduced to 72% after the pressing. As a result, a liquor is released from the peel which is then concentrated in the evaporator.

The wet peel then undergoes a drying process in rotating cylindrical dryers where hot gas is generated from the combustion of sugar cane bagasse or fuel oil. This gas enters the dryers at a temperature of approximately 800ºC exchanging heat with the bits of peel which will leave the dryers at a temperature of approximately 140ºC and a 10% to 12% humidity so that they may finally be pelletized. During this process humidity levels in the actual pellets are reduced to as low as 8% thus increasing the microbiological stability of the product and reducing fire hazards.

Citrus pulp pellets are used as a filler in beef or milk cattle feed . Its use should not exceed 30% of dry matter for each adult cow. As citrus pulp pellets absorb humidity it is vital that this feedstuff is kept in dry and ventilated storage facilities for no more than 60 days in order to avoid fermentation or mold.

Citrus Pulp Pellets Properties
Properties Value
Moisture (maximum) 12.0%                 
Gross protein (minimum) 5.0%                 
Ether lipid (minimum) 1.5%                 
Crude fiber (maximum) 14.0%                 
Mineral matter (maximum) 8.0%                 
Dioxin/Furan (maximum)
Expressed in minimum detection grade - Upperbound
500 pg/kg I - TEQ
Aflatoxins (maximum) 20 ppb
Brazilian exports of Citrus Pulp Pellets
Season Export volume
(in tons)
Season Export volume
(in tons)
1996/97 1,182,396 2002/03 1,003,971
1997/98 1,311,616 2003/04 875,937
1998/99 1,480,053 2004/05 986,479
1999/00 998,413 2005/06 687,421
2000/01 769,731 2006/07 806,231
2001/02 719,133 2007/08 809,076
Source: Secex